Molecular Formula | C6H9O6R |
Molar Mass | 278.2 |
Storage Condition | Room Temprature |
Physical and Chemical Properties | Ruthenium acetate is a black crystal and is mainly used as a catalyst or cocatalyst for various chemical reactions, such as hydrogenation, isomerization, carbonylation, etc. |
Shen Yafeng ,< a href = "https://xueshu.baidu.com/s?wd=author: (Lei Yuanjin) & tn = SE_baiduxueshu_c1gjeupa & ie = utf-8 & SC _f_para = SC _hilight = person" target = "_blank"> Lei Yuanjin ,< a href = "https://xueshu.baidu.com/s?wd=author: (Shen Shanwen) & tn = SE_baiduxueshu_c1gjeupa & ie = utf-8 & SC _f_para = SC _hilight = person" target = "_blank"> Shen Shanwen , Pan Zaifu
Summary:
Ru/C catalyst was prepared by impregnation reduction method with ruthenium acetate as precursor. Its activity was evaluated by hydrogenation of glucose to sorbitol under normal pressure, and characterized by transmission electron microscope (TEM) and X-ray diffraction. The activated carbon type, temperature, impregnation and reduction time, pH value were studied, effects of different precursors and organic additives on the activity of Ru/C catalyst. The results show that appropriate activated carbon particle size, large specific surface and pore volume are beneficial to the uniform distribution of Ru particles on the surface of activated carbon and improve the catalytic activity. The temperature of 80~90 ℃, the impregnation time of 8~10h, the reduction time of 6~8h and the pH value of 7~8 are conducive to the formation of Ru/C catalyst with high dispersion and high activity on the activated carbon carrier. The addition of organic additives makes the catalyst activity significantly higher than that of catalysts without organic additives. Different precursors have a great influence on the catalytic activity of Ru/C catalyst in this reaction. Ruthenium acetate is a good precursor for preparing Ru/C catalyst.
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keywords:
physical chemistry; Ruthenium acetate; Ru/C; Glucose hydrogenation; Iodine titration
DOI:
10.3969/j.issn.1004-0676.2009.01.008
cited:
Year:
2009